Search for: All records

Creators/Authors contains: "Forbes, Malcolm D. E."

« Prev Next »

Total Resources

4

Resource Type
Conference Paper

0

Conference Proceeding

0

Dataset

0

Journal Article

4

Workshop Report

0

Availability
Full Text / Resource Available

4

Citation Only

0

Save Results
Excel (limit 2000)
CSV (limit 5000)
XML (limit 5000)

Have feedback or suggestions for a way to improve these results?
!

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

Photochemical [2+4]‐Dimerization Reaction from the Excited State

https://doi.org/10.1002/ange.202316662

Ahuja, Sapna ; Baburaj, Sruthy ; Valloli, Lakshmy Kannadi ; Rakhimov, Sarvar Aminovich ; Manal, Kavyasree ; Kushwaha, Aakrati ; Jockusch, Steffen ; Forbes, Malcolm D. E. ; Sivaguru, Jayaraman ( December 2023 , Angewandte Chemie)

Abstract
Aryl‐maleimides undergo a novel [2+4]‐photodimerization instead of the expected [2+2]‐photodimerization under both direct irradiation with visible light and under sensitized energy transfer conditions. This new excited state reactivity in aryl‐maleimides is deciphered through photochemical, photophysical, and spectroscopic studies. The stereochemistry of the photodimer depends on the type of non‐bonding interactions prevalent during photodimerization which is in turn dictated by the substituents on the maleimide ring. More importantly, the stereochemistry of the photodimer formed is complementary to the product observed under thermal conditions.

more » « less
Photochemical [2+4]‐Dimerization Reaction from the Excited State

https://doi.org/10.1002/anie.202316662

Ahuja, Sapna ; Baburaj, Sruthy ; Valloli, Lakshmy Kannadi ; Rakhimov, Sarvar Aminovich ; Manal, Kavyasree ; Kushwaha, Aakrati ; Jockusch, Steffen ; Forbes, Malcolm D. E. ; Sivaguru, Jayaraman ( December 2023 , Angewandte Chemie International Edition)

Abstract
Aryl‐maleimides undergo a novel [2+4]‐photodimerization instead of the expected [2+2]‐photodimerization under both direct irradiation with visible light and under sensitized energy transfer conditions. This new excited state reactivity in aryl‐maleimides is deciphered through photochemical, photophysical, and spectroscopic studies. The stereochemistry of the photodimer depends on the type of non‐bonding interactions prevalent during photodimerization which is in turn dictated by the substituents on the maleimide ring. More importantly, the stereochemistry of the photodimer formed is complementary to the product observed under thermal conditions.

more » « less
Spinning Molecules, Spinning Spins: Modulation of an Electron Spin Exchange Interaction in a Highly Anisotropic Hyperfine Field

https://doi.org/10.1021/acsomega.1c03490

Brugh, Alexander M. ; Wang, Ruobing ; Therien, Michael J. ; Forbes, Malcolm D. E. ( October 2021 , ACS Omega)
Molecules, Photons, and Spins

https://doi.org/10.1002/cptc.201900181

Forbes, Malcolm D. E. ( July 2019 , ChemPhotoChem)